Pereira, Constantino Fernandez. 4 0
Predominance diagrams, a useful tool for the correlation of the precipitation-solubility equilibrium with other tonic equilibria. 6 6 - - - - - - - - . - . - 0 . - . - 0 .
ABSTRACT : The four types of ionic equilibria-acid-base, redox, precipitation, and complexation-have certain similarities, which has led some authors to develop a unified treatment of them. These authors have highlighted the common aspects and tried to find a systemization of the equilibria that would facilitate learning them. In this unified treatment, ionic reactions are interpreted as particle exchanges-involving protons, electrons, or ligands-between a donor and an acceptor of two conjugate pairs. The unified treatment proposes a graphic solution to the equilibria problems, using diagrams that employ the logarithm of the concentration of the exchanged particle as the variable. This paper presents the application of the precipitation-solubility equilibrium and describes the usefulness of such diagrams for solving solubility problems.
5
5
2 = =
2
2 --0------
6 --0-- 2 --------
0 2 --
--20------
Precipitation (Chemistry).;Separation (Technology).;Solution (Chemistry).;Solubility.;Ions.;Particles (Nuclear physics).;Chemical reactions.;Physics.;Chemistry, Physical and Theoretical. --------20--
--------20--
----2
QD1 .J826ce / 2
/ 2
/
/
Predominance diagrams, a useful tool for the correlation of the precipitation-solubility equilibrium with other tonic equilibria. 6 6 - - - - - - - - . - . - 0 . - . - 0 .
ABSTRACT : The four types of ionic equilibria-acid-base, redox, precipitation, and complexation-have certain similarities, which has led some authors to develop a unified treatment of them. These authors have highlighted the common aspects and tried to find a systemization of the equilibria that would facilitate learning them. In this unified treatment, ionic reactions are interpreted as particle exchanges-involving protons, electrons, or ligands-between a donor and an acceptor of two conjugate pairs. The unified treatment proposes a graphic solution to the equilibria problems, using diagrams that employ the logarithm of the concentration of the exchanged particle as the variable. This paper presents the application of the precipitation-solubility equilibrium and describes the usefulness of such diagrams for solving solubility problems.
5
5
2 = =
2
2 --0------
6 --0-- 2 --------
0 2 --
--20------
Precipitation (Chemistry).;Separation (Technology).;Solution (Chemistry).;Solubility.;Ions.;Particles (Nuclear physics).;Chemical reactions.;Physics.;Chemistry, Physical and Theoretical. --------20--
--------20--
----2
QD1 .J826ce / 2
/ 2
/
/