Consistent application of the Boltzmann distribution to residual entropy in crystals. 6
By: Kozliak, Evguemil I. 4 0 16 [, ] | [, ] |
Contributor(s): 5 6 [] |
Language: Unknown language code Summary language: Unknown language code Original language: Unknown language code Series: ; 46Edition: Description: Content type: text Media type: unmediated Carrier type: volumeISBN: ISSN: 2Other title: 6 []Uniform titles: | | Subject(s): -- 2 -- 0 -- -- | -- 2 -- 0 -- 6 -- | 2 0 -- | -- -- 20 -- | | -- -- Maxwell - Boltzmann distribution law.;Thermodynamics.;Distribution (Probability theory).;Kinetic theory of gases.;Molecular theory.;Statistical mechanics.;Chemistry, Physical and Theoretical.;Quantum theory.;Physics. -- -- 20 -- | -- -- -- 20 -- --Genre/Form: -- 2 -- Additional physical formats: DDC classification: | LOC classification: | QD1 .J826ce | 2Other classification:| Item type | Current location | Home library | Collection | Call number | Status | Date due | Barcode | Item holds |
|---|---|---|---|---|---|---|---|---|
| Book | PLM | PLM Periodicals Section | Periodicals | QD1 (Browse shelf) | Available | PER 1320CA |
ABSTRACT : Four different approaches to residual entropy (the entropy remaining in crystals comprised of nonsymmetric molecules like CO, N2O, FClO3, and H2O as temperatures approach 0 K) are analyzed and a new method of its calculation is developed based on application of the Boltzmann distribution. The inherent connection of all four methods (based on combinatorics, thermodynamics, mixing, or statistical mechanicsâ€probabilities) to one another is shown. They yield the same numerical value of residual entropy when the “frozen-in†energy difference between the possible intermolecular interactions for different molecular arrangements (configurations) is negligible as compared to kBTfusion. 56
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