Kozliak, Evguemil I.  4  0   <br/><br/>
Consistent application of the Boltzmann distribution to residual entropy in crystals.        6 
       6     

 -   
 -     
 -         
 -   
 -   
 - 
 - 
 -         .
 -     .
 -          0   .
 -         .
 -  0       .
<br/><br/>   ABSTRACT :  Four different approaches to residual entropy (the entropy remaining in crystals comprised of nonsymmetric molecules like CO, N2O, FClO3, and H2O as temperatures approach 0 K) are analyzed and a new method of its calculation is developed based on application of the Boltzmann distribution. The inherent connection of all four methods (based on combinatorics, thermodynamics, mixing, or statistical mechanicsâ€probabilities) to one another is shown. They yield the same numerical value of residual entropy when the “frozen-in†energy difference between the possible intermolecular interactions for different molecular arrangements (configurations) is negligible as compared to kBTfusion. 
<br/><br/>
<br/><br/>      
<br/><br/>   5 
<br/><br/>      
<br/><br/>        
<br/><br/>      
<br/><br/><br/> <br/> <br/> <br/> <br/> <br/> <br/> 
<br/><br/><br/>5     
<br/><br/><br/> <br/>   
<br/><br/><label>ISBN: </label>  
<br/><br/><label>ISSN: </label>2 
 =   
 =   
<br/><br/><label>Standard No.: </label>        
<br/><br/><label>Publisher. No.: </label>  
<br/><br/><label>Source: </label>        
<br/><br/><label>LCCN: </label>
<br/><br/><label>Nat. Bib. No.: </label> 2 
<br/><br/><label>Nat. Bib. Agency Control No.: </label>    
<br/><br/><label>Subjects--Personal Names: </label><br/>     2     --0------
<br/><br/><label>Subjects--Corporate Names: </label><br/>     6 --0-- 2 --------
<br/><br/><label>Subjects--Meeting Names: </label><br/><br/> 0    2 --
<br/><br/><label>Subjects--Uniform Titles: </label><br/>  --20------
<br/><br/><label>Subjects--Chronological Terms: </label><br/> 
<br/><br/><label>Subjects--Topical Terms: </label><br/>Maxwell - Boltzmann distribution law.;Thermodynamics.;Distribution (Probability theory).;Kinetic theory of gases.;Molecular theory.;Statistical mechanics.;Chemistry, Physical and Theoretical.;Quantum theory.;Physics.    --------20--
<br/><br/><label>Subjects--Geographic Terms: </label><br/>--------20--
<br/><br/><label>Index Terms--Genre/Form: </label><br/>----2
<br/><br/><label>LC Class. No.: </label>QD1 .J826ce  / 2 
<br/><br/><label>Dewey Class. No.: </label> / 2 
<br/><br/><label>National Agricultural Library Call No.: </label> /  
<br/><br/><label>National Library of Medicine Call No.: </label> /  
<br/><br/><label>Gov. Doc. Class. No.: </label>